TiN nanoparticles: small size-selected fabrication and their quantum size effect
نویسندگان
چکیده
Size-selected TiN nanoclusters in the range of 4 to 20 nm have been produced by an ionized cluster beam, which combines a glow-discharge sputtering with an inert gas condensation technique. With this method, by controlling the experimental conditions, it was possible to produce nanoparticles with a high control in size. The size distribution of TiN nanoparticles was determined before deposition by mass spectroscopy and confirmed by atomic force microscopy. The size distribution was also analyzed using a high-resolution transmission electron micrograph. The photoluminescence [PL] spectra of TiN nanoparticles at different sizes were also experimentally investigated. We reported, for the first time, the strong visible luminescence of TiN nanoparticles on Si (111) wafer due to the reduced size. We also discussed the PL intensity as a function of the nanoparticle size distribution.
منابع مشابه
Synthesis and characterization of SnO2 nanoparticles by Co-Precipitation method
Tin oxide (SnO2)nanoparticles were synthesized by co-precipitation method and the synthesized nanoparticles were annealed at different temperatures for characterization. The powders were investigated with X-ray diffraction, scanning electron microscopy and optical spectroscopy. The structural characterization was carried out by X-ray diffraction which confirms the crystalline nature ...
متن کاملMicrowave–Assisted Hydrothermal Synthesis and Optical Characterization of SnO2 Nanoparticles
Semiconductor nanoparticles exhibit size dependent properties due to quantum confinement effect that are not present in their bulk counterparts. In this work, extremely fine and pure SnO2 nanoparticles of ~1.1 nm size were synthesized by a solution process, in which amorphous precipitate of SnO2 was crystallized by microwave heating. The particles sizes varied from ~1.1 to ~2.7 nm. By XRD analy...
متن کاملFabrication and evaluation of gelatin nanoparticles for delivering of anti - cancer drug
The aim of present study was to prepare gelatin nanoparticle for drug and gene delivery applications. These nanoparticles were prepared by two-step desolvation method. The body distribution of colloidal drug delivery systems was mainly influenced by two physicochemical properties namely particle size and surface characteristics. The influence of several factors on the fabrication process includ...
متن کاملInfluence of Solution Temperature and pH on Size and Morphology Improvement of Chitosan Nanoparticles as Protein Delivery Vehicles
In recent years, utilization of chitosan /tripolyphosphate nanoparticles has been considered greatly as protein delivery vehicles. Effects of a variety of factors on final characteristics of nanoparticles have been studied by many investigators. Although, the objective of this study was to achieve smaller chitosan nano carriers via changing fabrication parameters such as pH and temperature and ...
متن کاملSize-selected agglomerates of SnO2 nanoparticles as gas sensors
The effect of nanoparticle structure on gas sensing performance is investigated. Size-selected nanostructured SnO2 agglomerate particles for gas sensors were made by scalable flame spray pyrolysis. These particles were polydisperse up to 12 m in diameter and consisted of primary particles of 10 nm in grain and crystal size as measured by transmission electron microscopy, x-ray diffraction, and ...
متن کامل